4.8 Article

Stereoselective Installation of Five Contiguous Stereogenic Centers in a Double Aldol-Tishchenko Cascade and Evaluation of the Key Transition State through DFT Calculation

Related references

Note: Only part of the references are listed.
Article Chemistry, Organic

Mechanism and Origins of Stereoselectivity of the Aldol-Tishchenko Reaction of Sulfinimines

Aneta Turlik et al.

Summary: Density functional theory computations have elucidated the mechanism and origins of stereoselectivity in McGlacken's aldol-Tishchenko reaction, with variations of stereochemical outcome dependent on the nature of the ketone starting materials used. The intramolecular hydride transfer step is the key rate- and stereochemistry-determining step in this process.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Article Multidisciplinary Sciences

A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group

Miao Zhan et al.

NATURE COMMUNICATIONS (2020)

News Item Chemistry, Multidisciplinary

Easy as one, two, three

Laura Castoldi et al.

NATURE CHEMISTRY (2018)

Article Multidisciplinary Sciences

Asymmetric phosphoric acid-catalyzed four-component Ugi reaction

Jian Zhang et al.

SCIENCE (2018)

Article Chemistry, Multidisciplinary

Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of beta-Substituted Styrenes

Biying Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Chemistry, Multidisciplinary

Theory and Modeling of Asymmetric Catalytic Reactions

Yu-hong Lam et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Review Chemistry, Multidisciplinary

Computing organic stereoselectivity - from concepts to quantitative calculations and predictions

Qian Peng et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Pot economy and one-pot synthesis

Yujiro Hayashi

CHEMICAL SCIENCE (2016)

Article Chemistry, Multidisciplinary

Computational Organic Chemistry: Bridging Theory and Experiment in Establishing the Mechanisms of Chemical Reactions

Gui-Juan Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Organic

Asymmetric Aldol-Tishchenko Reaction of Sulfinimines

Vera M. Foley et al.

ORGANIC LETTERS (2015)

Article Biochemistry & Molecular Biology

Escape from Flatland 2: complexity and promiscuity

Frank Lovering

MEDCHEMCOMM (2013)

Article Chemistry, Multidisciplinary

Organocatalytic one-pot asymmetric synthesis of functionalized tricyclic carbon frameworks from a triple-cascade/Diels-Alder sequence

Dieter Enders et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Review Chemistry, Multidisciplinary

1,3-Aminoalcohols and their derivatives in asymmetric organic synthesis

Susan M. Lait et al.

CHEMICAL REVIEWS (2007)

Article Multidisciplinary Sciences

Control of four stereocentres in a triple cascade organocatalytic reaction

Dieter Enders et al.

NATURE (2006)

Review Chemistry, Multidisciplinary

Asymmetric multicomponent reactions (AMCRs): The new frontier

DJ Ramon et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

Article Chemistry, Multidisciplinary

Development and application of a new general method for the asymmetric synthesis of syn- and anti-1,3-amino alcohols

T Kochi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Review Chemistry, Multidisciplinary

Tandem reactions, cascade sequences, and biomimetic strategies in total synthesis

KC Nicolaou et al.

CHEMICAL COMMUNICATIONS (2003)

Article Chemistry, Multidisciplinary

Asymmetric synthesis of syn- and anti-1,3-amino alcohols

T Kochi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)