Journal
OPTICAL MATERIALS
Volume 119, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.optmat.2021.111362
Keywords
Perovskite; Zinc oxy-sulphide; Copper thiocyanate; SCAPS-1D
Categories
Funding
- University of Jammu [RA/SA/URS-PhD/245/20/7658-60]
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The study proposed a perovskite solar cell structure with zinc oxy-sulphide as the electron transport layer and copper thiocyanate as the hole transport layer, achieving a power conversion efficiency of 25.94% through simulation and optimization of parameters. The research results serve as a reference for the development of novel perovskite solar cells that are environmentally safe, lead-free, and comparable in efficiency to lead-based counterparts.
Zinc oxy-sulphide (ZnO1-xSx) has proven to be the most promising material for electron transport layer (ETL) as a replacement of CdS in thin film and perovskite solar cells due to its ability to tune the bandgap energy (2.7-3.8 eV). FASnI(3) (CH4N2SnI3) based perovskite solar cells are found to be more efficient and stable than their MASnI(3) counterparts because of its wider bandgap (1.41 eV) and better temperature stability. In this paper, FASnI(3) based perovskite solar cell employing zinc oxy-sulphide (Zn (O-0.3, S-0.7)) as ETL and copper thiocyanate (CuSCN) as HTL is presented. The proposed structure FTO/Zn(O-0.3, S-0.7)/FASnI(3)/CuSCN/Au has been simulated using SCAPS-1D software. The parameters from various experimental and theoretical reported works were used to simulate the proposed solar cell and it resulted in 14.46% of power conversion efficiency (PCE). In order to investigate the impact of active layer on the performance of the proposed device, the parameters of active layer like thickness and defect density have been varied. Furthermore, parameters such as electron affinity, doping density and thickness of ETL and HTL respectively have also been varied to examine their influence on the output device parameters and optimized results deduced accordingly. Finally, the device simulation with the optimized parameters has resulted in improved output parameters with V-OC of 1.0859 V, J(SC) of 28.12 mAcm(-2), FF of 84.96% and PCE of 25.94%, thus, paving the way for novel perovskite solar cells employing tin which are environmentally safe being lead free and have efficiency comparable tothe lead based counterparts.
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