4.6 Article

Ultra-broadband high solar absorption in checkerboard-shaped titanium nitride plasmonic metastructures

Journal

OPTICAL MATERIALS
Volume 116, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.optmat.2021.111117

Keywords

Metastructures; Finite-difference time-domain method; Plasmonic hybridization; Checkerboard-shaped pattern; Ultra-broadband absorption

Funding

  1. University of Texas at Dallas startup fund, United states
  2. National Science Foundation, United states [CBET-1937949]

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The use of titanium nitride in a metastructure design for efficient light absorption in solar energy harvesting applications has been demonstrated in this study. Through systematic optimization of the metastructure's geometric parameters using FDTD simulations, high absorption rates across a broad spectral range have been achieved, showing great potential for solar energy harvesting applications.
Titanium nitride (TiN) has been proved as an efficient, refractory plasmonic material in solar energy harvesting applications. In this paper, we demonstrate the design of a simple metastructure, including a checkerboardshaped TiN grating layer embedded in a SiO2 dielectric layer and a TiN film as a reflective layer, to realize highly efficient light absorption for solar energy harvesting. After systematically optimizing the geometric parameters of the metastructure by finite-difference time-domain (FDTD) simulations, we achieve high absorption rates with an average value up to 97% across an ultra-broad spectral range from 0.4 to 2.0 mu m, significantly extending the light absorption ranges reported in prior work. Detailed analyses of the electric field elucidate that the unique checkerboard-shaped pattern results in plasmon hybridization between the adjacent TiN nano-ribbons at different resonant wavelengths. Combined with the high absorption due to the dielectric-like nature of TiN and Fabry-Perot resonances, the proposed metadevice achieves excellent light absorption performance within the solar spectrum, exhibiting great potential for various solar energy harvesting applications.

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