4.6 Article

NiCo alloy/C nanocomposites derived from a Ni-doped ZIF-67 for lightweight microwave absorbers

Journal

NANOTECHNOLOGY
Volume 32, Issue 38, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/1361-6528/ac0ac3

Keywords

ordered mesoporous carbon; microwave absorption; in situ pyrolysis; NiCo alloy

Funding

  1. Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering [2021-K19]
  2. Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL202003SIC]
  3. Key Technologies R&D Program of Anhui Province of China (2021)
  4. Shenzhen Technology University (SZTU)
  5. Natural Science Foundation of Top Talent of SZTU [2019010801002]

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NiCo alloy/C with rhombic dodecahedron structure and superior microwave absorption performance was prepared using ZIF-67 as raw material. By adjusting the doping amount of Ni and pyrolysis temperature, the impedance matching of NiCo alloy/C was improved. The composite material showed potential to be a lightweight microwave absorber with high absorption properties.
In this work, we prepared NiCo alloy/C with rhombic dodecahedron structure and superior microwave absorption performance by using ZIF-67 as the raw material. The rhombic dodecahedron NiCo alloy/C was with rough particles on the surface was photographed by field emission scanning electron microscopy. By adjusting the doping amount of Ni and the temperature of pyrolysis, improved the impedance matching of NiCo alloy/C. Specifically, NiCo alloy/C exhibits a minimum reflection loss of -65.48 dB at 13.48 GHz, while the thickness is 1.63 mm. Defects introduced in the Ni doping process and the special rhombic dodecahedral structure can cause multiple loss mechanisms. Therefore, this NiCo alloy/C composite has the potential to be a potential microwave absorber material with lightweight and high microwave absorption properties.

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