4.6 Article

First Evidence of Earth Wax Inside the Casting Molds from the Roman Era

Journal

MOLECULES
Volume 26, Issue 14, Pages -

Publisher

MDPI
DOI: 10.3390/molecules26144259

Keywords

earth wax; ceresin; soot; X-ray fluorescence; gas chromatography; Roman era; mold; mass spectrometry; ion mobility

Funding

  1. ERDF/ESF [CZ.02.1.01/0.0/0.0/17_048/0007378]
  2. Grant Agency of Czech Republic [17-17346S]

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This study focused on analyzing material composition and organic residues in molds from the Moravian region dating back to the Roman era. The presence of earth wax in the molds suggests the use of wax models in the production process. This research also marks the first application of ASAP-IMS-HRMS in archaeological studies.
This research was focused on the analysis of material composition and organic residues present in three molds found in the Moravian region (Czech Republic) belonging to the Roman era. X-ray fluorescence spectroscopy pointed out the possible remelting of Roman objects in Barbarian territory. The analysis of organic residues retrieved from the internal part of mold #2 by pyrolysis-gas chromatography/mass spectrometry proved the presence of ozokerite wax (earth wax). Consequent analysis of this organic residue by Atmospheric Solids Analysis Probe-ion mobility spectrometry-high-resolution mass spectrometry (ASAP-IMS-HRMS) confirmed the presence of ceresin, the main component of ozokerite. Ceresin was also detected in a sample of the organic residue from mold #1. Note that this is the first application of ASAP-IMS-HRMS in archaeological research. The remains of earth wax in molds suggest the production of wax models as an intermediate stage for the production of lost-wax ceramic casting molds.

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