4.6 Review

The Surge of Metal-Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

Journal

MOLECULES
Volume 26, Issue 18, Pages -

Publisher

MDPI
DOI: 10.3390/molecules26185713

Keywords

water treatment; electrochemical advanced oxidation processes (EAOPs); photoelectrocatalysis; electro-Fenton; capacitive deionization (CDI); electrocatalysis; metal-organic framework (MOF); carbonized metal-organic framework (MOFC); zeolitic imidazolate frameworks (ZIF)

Funding

  1. FONDECYT project [1210343]
  2. National Science Foundation Nanosystems Engineering Research Center on Nanotechnology-Enabled Water Treatment [EEC-1449500]
  3. U.S. DOE [DEAC05-76RL01830]

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This review highlights the use of Metal-organic-frameworks (MOFs) in environmental electrochemistry, showcasing their superior performance compared to traditional materials in various water remediation technologies. It discusses the synthesis of MOFs and their application in different degradation reactions, as well as provides perspectives for the future development of MOF-derived materials in electrified water treatment.
Metal-organic-frameworks (MOFs) are emerging materials used in the environmental electrochemistry community for Faradaic and non-Faradaic water remediation technologies. It has been concluded that MOF-based materials show improvement in performance compared to traditional (non-)faradaic materials. In particular, this review outlines MOF synthesis and their application in the fields of electron- and photoelectron-Fenton degradation reactions, photoelectrocatalytic degradations, and capacitive deionization physical separations. This work overviews the main electrode materials used for the different environmental remediation processes, discusses the main performance enhancements achieved via the utilization of MOFs compared to traditional materials, and provides perspective and insights for the further development of the utilization of MOF-derived materials in electrified water treatment.

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