Journal
FUEL
Volume 185, Issue -, Pages 73-84Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2016.07.069
Keywords
Sugarcane bagasse; Pentose ethanol; Hydrothermal pretreatment; Post-hydrolysis; Xylooligosaccharides
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Funding
- FAPESP - Sao Paulo Research Foundation [2013/05369-2]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [13/05369-2] Funding Source: FAPESP
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Hydrothermal pretreatment solubilizes about 65% of the hemicelluloses in sugarcane bagasse. However, nearly 80% of the xylose recovered from the hemicellulosic hydrolysate is present as xylooligosaccharides (XO's), which cannot be directly fermented into pentose (C5) ethanol. In this work a kinetic study of the post hydrolysis process considering the use of three acids - sulfuric, oxalic and maleic - was performed. Xylose and furfural post-hydrolysis profiles showed the reaction time in which xylose peaked with minimum furfural production. Among the three studied acids, sulfuric acid showed the fastest kinetics of post-hydrolysis with XO's being fully hydrolyzed in less than 1 h reaction time. C5 fermentation experiments showed that the detoxified post-hydrolysates fermented with ethanol yields ranging from 0.10 to 0.31 g ethanol g(-1) reducing sugars. Most samples were fermented from 48 to 72 h of experiment with productivities ranging from 0.02 to 0.43 g.L-1.h(-1). (C) 2016 Elsevier Ltd. All rights reserved.
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