Thermal Stability of Aluminum-Nickel Binary Alloys Containing the Al-Al3Ni Eutectic

The capability of Al-Ni binary alloys containing from 3 to 11 wt pct Ni and ranging from hypo-to hypereutectic compositions to retain strength at high temperatures was assessed through the uniaxial compression up to 500 degrees C and correlated with their solidification characteristics, phase composition and microstructure. The Al-Ni alloys, strengthened by the Al3Ni eutectic and proeutectic phases, at room temperature reached the yield stress of 70 to 100 MPa, being higher than 26 MPa measured for pure Al but well below 170 MPa achieved for the A380 (Al-8Si-3Cu, wt pct) alloy, tested under identical conditions. During high-temperature compression, the yield stress of Al-Ni alloys reduced at a steady rate with temperature, retaining at 400 degrees C and 500 degrees C about 50 pct and 25 pct, respectively, of its initial room temperature level. This yield stress reduction did not correlate with the low coarsening rate of Al3Ni phases and high hardness retention ratio of 75 to 80 pct, measured after 168 h heating at 500 degrees C. Although the higher Ni content resulted generally in the higher yield stress, the contribution of Al3Ni phases to retaining the alloy strength reduced with testing temperature; at all testing temperatures the finer Al3Ni eutectic phase was more effective than the coarser Al3Ni proeutectic phase, with an influence of the latter disappearing completely above 300 degrees C. An implication of the limited role of Al3Ni eutectic and proeutectic phases in room temperature strengthening of Al-Ni binary alloys and in retaining their strength at increased temperatures for development of novel aluminum alloys is discussed.

Automated summary

Al-Ni binary alloys containing Al3Ni eutectic and proeutectic phases showed the capability to retain strength at high temperatures, with the contribution of Al3Ni phases decreasing as temperature increased, especially above 300 degrees C. The finer Al3Ni eutectic phase was found to be more effective in strengthening the alloy compared to the coarser Al3Ni proeutectic phase, which lost its influence completely above 300 degrees C.