Effect of NbC and VC carbides on microstructure and strength of high-strength low-alloyed steels for oil country tubular goods

High-strength low-alloyed (HSLA) steels for oil country tubular goods (OCTGs) are usually microalloyed with niobium (Nb) and vanadium (V). In this work, the microstructure and strength of HSLA steels with different Nb and V contents were studied with the purpose of investigating the role of NbC and VC carbides. The results showed that NbC carbides were responsible for restraining the growth of prior austenite grains, and when the austenitizing temperature was below 910 degrees C, it has been found that the prior austenite grain size was similar in steels with 0.02 and 0.006 wt% Nb addition. VC carbides could impede dislocation annihilation and refine Crrich carbides and martensitic blocks during tempering. Moreover, VC carbides mainly contributed to the tempering softening resistance so that the V-bearing steels exhibited a higher strength than the V-free steel after tempering at 690 degrees C-730 degrees C. To illustrate the high tempering softening resistance of V-bearing steels, the changes in various strengthening contributions induced by V addition were quantitatively evaluated. The calculation results indicated that the main reason for the high tempering softening resistance of V-bearing steels was precipitation strengthening by nanosized VC carbides, in contrast to dislocation strengthening, substructure strengthening, and precipitation strengthening due to the refinement of Cr-rich carbides.

Automated summary

Vanadium and niobium have significant effects on the strength and microstructure of HSLA steels, with NbC and VC carbides playing key roles in inhibiting the growth of prior austenite grains and refining carbides and martensitic blocks. V-bearing steels exhibit higher strength after tempering, mainly due to the resistance to tempering softening provided by VC carbides.