4.7 Article

Oxygen addition in biomedical Ti-Nb alloys with low Nb contents: Effect on the microstructure and mechanical properties

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2021.141750

Keywords

Titanium alloys; Interstitial; Hardness; Compressive strength; Young's modulus

Funding

  1. Brazilian research funding agency FAPESP (Sao Paulo Research Foundation) [2019/146561]
  2. Brazilian research funding agency CNPq (National Council for Scientific and Technological Development)
  3. Brazilian research funding agency CAPES (Coordination of Superior Level Staff Improvement)

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In this study, the influence of oxygen content on the microstructure and mechanical properties of Ti-Nb alloys was evaluated. The results showed that increasing oxygen content slightly affected the thickness of alpha plates and beta-transus, but improved hardness and compressive yield stress. Solid-solution strengthening by Nb and oxygen, along with microstructural refinement by Nb addition, were responsible for these improvements.
Ti-Nb alloys have been widely researched for biomedical applications because of their excellent mechanical properties, corrosion resistance, and superior biocompatibility. In this investigation, the influence of oxygen content on the microstructure and mechanical properties of Ti-Nb alloys with relatively low Nb contents was evaluated. Arc-melted Ti-Nb-O ingots (Nb contents were 15, 17.5, 20, and 22.5 wt% and O contents were 0.15, 0.25, and 0.40 wt%) were hot-rolled and solution-treated at 1200 degrees C for 1 h, followed by furnace cooling. These samples were characterized by scanning electron microscopy, differential scanning calorimetry, compression tests, and measuring hardness and Young's modulus. The furnace-cooled alloys exhibited typical alpha + beta microstructures, in which the thickness of the alpha plates decreased with increasing Nb content and increased slightly with increasing oxygen content. A similar behavior was observed for the apparent beta-transus, which decreased with increasing Nb content, and increased with increasing oxygen content. The obtained hardness and 0.2% compressive yield stress improved with increasing concentrations of alloying elements. This was due to the solidsolution strengthening promoted by Nb and oxygen, and microstructural refinement induced by Nb addition. The Young's modulus was found to increase very slowly with increasing oxygen content. Owing to the enhancement in yield stress and the small change in elastic modulus with increasing oxygen content, alloys can be designed and produced with high mechanical strength/Young's modulus ratios, favoring their application as biomaterials.

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