4.6 Article

Zn-Fe Flower-like nanoparticles growth by gas condensation

Journal

MATERIALS LETTERS
Volume 297, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2021.129916

Keywords

Bimetallic; STEM; EELS tomography; Oxygen scavengers; Nanomaterial

Funding

  1. Portuguese Foundation for Science and Technology (FCT) [UIDB/04650/2020]
  2. FEDER (PT2020) [POCI-01-0145-FEDER-030789]
  3. project NANOXY-PACK

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This study demonstrates a fast and simple method to obtain flower-like Zinc-Iron nanoparticles using a hybrid system combining conventional magnetron sputtering and a cluster beam source. Characterization of morphology and structure was done by STEM, while chemical composition was evaluated by EDS and EELS. Molecular dynamic simulations revealed the formation mechanisms of the flower-like nanoparticles during simultaneous production.
Bimetallic nanoparticles have gained attention in the last decade due to their unusual characteristics compared to monometallic counterparts. However, production of such particles with controlled morphologies and composition needs to be explored and the mechanisms understood. In this work, we demonstrate a fast and simple process to obtain flower-like Zn-Fe (Zinc-Iron) nanoparticles (NPs) using a hybrid system based on the combination of conventional magnetron sputtering and a cluster beam source. The morphology and structure were characterized by Scanning transmission electron microscopy (STEM), while the chemical composition was evaluated by simultaneous acquisition of Energy-dispersive X-ray spectroscopy (EDS) and Electron energy loss spectroscopy (EELS). Besides, molecular dynamic simulations were used to model the nanoparticle collisions during the simultaneous production, revealing the formation mechanisms of the flower-like nanoparticles. (c) 2021 Published by Elsevier B.V.

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