Journal
MATERIALS LETTERS
Volume 293, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2021.129732
Keywords
Phase transformation; Shape memory materials; Ti-Ni-Cu-Hf; Thermodynamic and kinetics
Funding
- National Natural Science Foundation of China [51801023, 51871080, 51931004]
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The study investigated the martensitic transformation and its kinetics in the Ti-Ni-Cu-Hf shape memory alloy, revealing a strong dependence of transformation kinetics on cooling rate. The apparent activation energy was calculated and the variation of transition activation energy for a specific martensite fraction was studied to further characterize the martensitic transformation kinetics.
The purpose of the paper was to investigate the martensitic transformation and its kinetic of the Ti-Ni-Cu-Hf shape memory alloy. The Ti47Ni44Cu6Hf3 alloy would undergo a reversible B2 <-> B19' martensitic transformation during thermal cycling process. The apparent activation energy was calculated based on seven different DSC cooling curves. A strong cooling rate dependence of martensitic transformation kinetics was observed and the corresponding mechanism was discussed. Moreover, the variation of transition activation energy for a specific martensite fraction was studied to further characterize the martensitic transformation kinetics. (C) 2021 Elsevier B.V. All rights reserved.
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