4.7 Article

Effects of Nb or (Nb plus Mo) alloying on Charpy impact, bending, and delayed fracture properties in 1.9-GPa-grade press hardening steels

Journal

MATERIALS CHARACTERIZATION
Volume 176, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2021.111133

Keywords

delayed fracture; U-bending and HCl immersion test; Charpy impact energy; peak-load bending angle; complex carbide precipitation; grain refinement; 9-GPa-grade ' 32MnB5' press hardening steel

Funding

  1. CBMM
  2. Brain Korea 21 PLUS Project for Center for Creative Industrial Materials
  3. Korea University

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By alloying Nb or (Nb + Mo) into 32MnB5 steel, the bending, impact, and delayed fracture properties of the steel can be significantly improved, with the synergistic effect of (Nb + Mo) alloying showing more pronounced enhancement. Nb alloying promotes the precipitation of nano-sized complex carbides, while Mo mainly affects grain refinement through a solute drag effect. These modifications result in a deviation in crack propagation path, leading to an increased Charpy impact energy.
In this study, effects of Nb or (Nb + Mo) alloying into a 1.9-GPa-grade 32MnB5 press hardening steel on Charpy impact, bending, and delayed fracture properties were investigated. All the properties were enhanced in the Nbor (Nb + Mo)-alloyed steels, especially in the (Nb + Mo)-alloyed steel. The Nb alloying worked for the precipitation of nano-sized complex carbides, thereby leading to the refinement of prior austenite grains by a Zener pinning effect. Mo also contributed to the grain refinement, while Mo affected it mostly in a solid-solution state by a solute drag effect. This grain refinement resulted in the more deviated crack propagation path and consequently in the more improved Charpy impact energy. The size reduction of Ti(C,N) inclusion due to the attachment of a small amount of Nb and Mo also improved the impact toughness. As well as microstructural effects, the lower residual stress due to the lower peak bending load by the Nb or (Nb + Mo) alloying contributed to the increase in H-induced delayed cracking time. Therefore, this study suggests that synergic interactions of Nb and Mo alloying would provide promising solutions for improving various properties, which should be more importantly considered under actually using environments such as mechanically forming and crashing for press hardening components, while satisfying the 1.9-GPa-strength 32MnB5 specification.

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