4.7 Article

Improving the mechanical performance of Cu-Cr alloy by dissolving Cu in the Cr second phase

Journal

MATERIALS CHARACTERIZATION
Volume 176, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2021.111104

Keywords

Cu-Cr alloy; Enhanced Cr second phase; Solid solubility; Mechanical properties

Funding

  1. National Natural Science Foundation of China-State Grid Joint Fund for Smart Grid [U1866203]
  2. National Natural Science Foundation of China [51906189]
  3. Key Scientific and Technological Innovation Team of Shaanxi province [2020TD-001]
  4. Natural Science Foundation of Shaanxi province [2020JQ-821]

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The limitations of the strengthening effects of Cr on Cu-Cr alloys due to low solid solubility of Cr in Cu phase have been addressed by enhancing the dispersion strengthening effect of the second phase Cr, using the levitation melting method. This novel strengthening mechanism has resulted in significant improvements in hardness and tribological properties of Cu-Cr alloys, demonstrating the potential to enhance mechanical performance.
The strengthening effects of Cr on Cu-Cr alloys are severely limited due to the relatively low solid solubility of Cr in Cu phase. Apart from the dissolved Cr, it should be noted that a high proportion of Cr in Cu matrix work as the second phase dispersion strengthening. To effectively improve the strengthening effect of Cr in Cu-Cr alloys, it is important to enhance the dispersion strengthening effect of the second phase Cr. In this work, the Cr phase could be strengthened by dissolving Cu atoms through the levitation melting method (LM), without additional alloying element was introduced. The results show that a maximum of Cu (0.46-0.54 wt%) is dissolved into Cr phase in Cu2Cr98 and Cu5Cr95 alloys. The corresponding hardness is 38% and 56% higher for Cu2Cr98 and Cu5Cr95 alloys compared with pure Cr, respectively. This novel strengthening mechanism of the enhanced Cr second phase is further applied in CuCr25 alloys. It is confirmed that the hardness is 57% higher for CuCr25 with enhanced Cr phase than that prepared using conventional methods. Furthermore, the significant strengthening effect is confirmed in the tribological properties. This strategy can be utilized to effectively enhance the mechanical performance of Cu-Cr alloys with high Cr content.

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