Journal
MACROMOLECULES
Volume 54, Issue 13, Pages 6045-6051Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.1c00864
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Funding
- International (Regional) Cooperation and Exchange Project (NSFC) [12050410231]
- National Science Foundation of China for Young Scientists of China (NSFC) [11904106]
- Fundamental Research Funds for the Central Universities [2019JQ05]
- Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices [2019B121203003]
- Recruitment Program of Guangdong [2016ZT06C322]
- Key-Area Research and Development Program of Guangdong Province [2020B010182002]
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This study demonstrated a general molecular design for emerging ferroelectric nematic liquid crystals by introducing large dipole moment and local bulkiness into rod-shaped mesogenic molecules. The extension of polar liquid crystal materials from small molecules to polymer systems provides vast technological potential for flexible supercapacitors, electro-optic devices, and nonlinear optical devices. The research also clarified that the magnitude of dipole moment plays a critical role in producing macroscopic polarity in side-chain liquid crystalline polymers.
Recently, we have demonstrated a general molecular design for emerging ferroelectric nematic liquid crystals by introducing large dipole moment and local bulkiness into rod-shaped mesogenic molecules. The giant dielectricity and strong nonlinear optic properties in the ferroelectric nematic liquid crystal materials could bring the vast technological potential for flexible supercapacitors, electro-optic devices, and nonlinear optical devices. Here, we extend the polar liquid crystal material from small molecules to polymer systems by elaborately manipulating the interplay between the side-chain joint position and dipole-dipole interaction. For this purpose, we developed three series of side-chain liquid crystalline polymers. We clarify that the polymers with side-jointed mesogens exhibit a polar nematic liquid crystalline phase with strong polarity confirmed by second harmonic generation, while the polymers with end-jointed mesogens self-assemble into a smectic A phase with no polarity. The magnitude of dipole moment was also critical for producing the macroscopic polarity in these side-chain liquid crystalline polymers.
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