Journal
MACROMOLECULES
Volume 54, Issue 12, Pages 5464-5472Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.1c00847
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Funding
- NSERC (Green Electronics Network and Discovery Grants)
- Fonds de recherche du Quebec nature et technologies (FRQNT)
- FRQNT
- NSERC
- IQST (Integrated Quantum Science and Technology) at the University of Stuttgart by the Carl Zeiss Foundation
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Water-processable self-doped polymers were synthesized using DHAP with water as a cosolvent, which showed air-stable electrical conductivities up to 50 S cm(-1) without post-treatment. The introduction of a counterion attached to the polymer backbone enhanced solubility and solution stability, making these polymers promising for a wide range of applications in printed electronics.
The synthesis of water-processable self-doped polymers has been achieved by direct (hetero)arylation polymerization (DHAP) using water as a cosolvent. The introduction of a counterion covalently attached to the backbone of the polymers enhanced their solubility and the stability of the solutions. Those polymers have shown air-stable electrical conductivities up to 50 S cm(-1) without the use of any post-treatment. The good water processability of these conducting polymers is promising for printed electronics in a wide range of applications.
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