Journal
MACROMOLECULAR REACTION ENGINEERING
Volume 15, Issue 6, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mren.202100022
Keywords
emulsion polymerization; monomer transport; transport limited
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The method of evaluating the Damkohler number for monomer transport in emulsion homopolymerization has been extended to copolymerization. It is found that monomers not limited by monomer transport in homopolymerization may become more limited in binary copolymerization, while monomers limited by monomer transport in homopolymerization may become less limited in binary copolymerization.
The method for evaluating the Damkohler number for monomer transport during emulsion homopolymerization is extended to copolymerization. It is shown that monomers that are not monomer-transport limited during homopolymerization may become more so during binary copolymerization, and monomers that are monomer-transport limited during homopolymerization may become less so during binary copolymerization.
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