Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 42, Issue 14, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202100166
Keywords
benzoyl azide; Curtius rearrangement; ligation; photochemistry; surface modification
Categories
Funding
- Scientific and Technological Research Council of Turkey [120C121]
- Istanbul Technical University Research Fund [42851]
- Council of Higher Education of Turkey
- TUBITAK 2211-A National Graduate Scholarship
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This study demonstrates the use of a new photochemical ligation process as a versatile approach for various applications such as cross-linking polymerization, functionalization of polymer chain ends, and surface modification of different materials. The process involves the formation of urethane linkages through the reaction of photochemically in situ generated isocyanates with hydroxyl moieties. The intermediates and obtained materials were characterized using NMR, FTIR, TGA, and TEM analyses, showing the potential for future applications in fabricating complex macromolecular structures, biomaterials, and gels.
Various ligation processes have recently become a powerful tool in synthetic polymer chemistry. Herein, the use of a new photochemical ligation process as a versatile approach for the cross-linking polymerization, functionalization of polymer chain ends, and surface modification of various materials such as silica and graphene oxide, is demonstrated. The process is based on the formation of urethane linkages by the reaction of photochemically in situ generated isocyanates from benzoyl azides with hydroxyl moieties in the presence of organobase, bicyclo[2.2.2]-1,4-diazaoctane (DABCO) under ambient conditions. The intermediates and obtained materials are characterized by NMR, FTIR, TGA, and TEM analyses. It is believed that this simple and efficient ligation process will expand future applications to fabricate complex macromolecular structures, biomaterials, and gels.
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