Oxygen-Selective Diffusion-Bubbling Membranes with Core-Shell Structure: Bubble Dynamics and Unsteady Effects

Oxygen is the second-largest-volume industrial gas that is mainly produced using cryogenic air separation. However, the state-of-the-art cryogenic technology thermodynamic efficiency has approached a theoretical limit as near as is practicable. Therefore, there is stimulus to develop an alternative technology for efficient oxygen separation from air. Mixed ionic electronic-conducting (MIEC) ceramic membrane-based oxygen separation technology could become this alternative, but commercialization aspects, including cost, have revealed inadequacies in ceramic membrane materials. Currently, diffusion-bubbling molten oxide membrane-based oxygen separation technology is being developed. It is a potentially disruptive technology that would propose an improvement in oxygen purity and a reduction in capital costs. Bubbles play an important role in ensuring the oxygen mass transfer in diffusion-bubbling membranes. However, there is not sufficient understanding of the bubble dynamics. This understanding is important to be able to control transport properties of these membranes and assess their potential for technological application. The aim of this feature article is to highlight the progress made in developing this understanding and specify the directions for future research.

Automated summary

Oxygen, the second-largest industrial gas, is mainly produced using cryogenic air separation technology. However, the current low-temperature technology has reached its limit, leading to the need for alternative technologies. MIEC ceramic membranes and diffusion-bubbling molten oxide membranes show promise, but cost and performance issues need to be addressed. Understanding bubble dynamics is crucial for controlling the transport properties of these membranes.