Transmittance enhancement of spark plasma sintered CaF2 ceramics by preheating commercial powder

Spark plasma sintering (SPS) is a convenient approach for preparing transparent CaF2 ceramics. However, carbon contamination is a key issue that should be addressed to achieve high transparency. In this study, a commercially available CaF2 powder was preheated under vacuum before performing SPS to mitigate carbon contamination. During the preheating of the CaF2 powder, impurities adsorbed on the particle surface, such as H2O, CO2, and O2, are desorbed. Moreover, the interdiffusion of carbon contaminants is suppressed due to the pre-sintering of the raw powder. The in-line transmittance of the CaF2 ceramic prepared from the preheated powder increased to 85 % at the wavelength of 1100 nm, which is 38 % higher than that of the ceramic prepared without preheating. In addition, the in-line transmittance increased with increasing grain size of the ceramic, possibly because of the decrease in the number of scattering sources with the reduction in the grain boundary fraction.

Automated summary

Preheating CaF2 powder under vacuum before Spark Plasma Sintering can reduce carbon contamination and improve transparency. The in-line transmittance of CaF2 ceramics increases with increasing grain size, possibly due to a decrease in scattering sources.