4.6 Article

In Situ Measurement of Temperature Distributions in a Li-ion Cell during Internal Short Circuit and Thermal Runaway

Journal

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 168, Issue 9, Pages -

Publisher

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/ac1d7b

Keywords

thermal runaway; internal short circuit; temperature distribution; in situ measurement; Batteries Li-ion; battery safety

Funding

  1. Ford Motor Company [URP 2018-7158R]
  2. University of Alabama in Huntsville
  3. Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office [DE-AC05-00OR22725]

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The study reports in situ measurement of temperature distributions in a 2.5-Ah pouch format Li-ion cell during internal short circuit (ISC) and thermal runaway, triggered by nail penetration. Highly non-uniform temperature distributions were observed, with details captured on the spread of thermal runaway and the critical role of internal short circuit resistance in the risk of thermal runaway.
Here we report in situ measurement of temperature distributions in a 2.5-Ah pouch format Li-ion cell during internal short circuit (ISC) and thermal runaway. The ISC and thermal runaway were triggered by nail penetration. The local temperatures were measured by embedded K type micro thermocouples in the middle layer of the experimental Li-ion cell. Highly non-uniform temperature distributions were observed during ISC and thermal runaway as compared with those during constant current discharging and external short circuit. The in situ measurement also captured details of how thermal runaway started from the ISC location and spread to the entire cell in a few seconds. Moreover, the comparison between ISC without thermal runaway and ISC with thermal runaway suggests that internal short circuit resistance plays a critical role in the risk of thermal runaway.

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