Ordered Mesoporous Silica Pyrolyzed from Single-Source Self-Assembled Organic-Inorganic Giant Surfactants

We report the preparation of hexagonal mesoporous silica from single-source giant surfactants constructed via dihydroxyl-functionlized polyhedral oligomeric silsesquioxane (DPOSS) heads and a polystyrene (PS) tail. After thermal annealing, the obtained well-ordered hexagonal hybrid was pyrolyzed to afford well-ordered mesoporous silica. A high porosity (e.g., 581 m(2)/g) and a uniform and narrow pore size distribution (e.g., 3.3 nm) were achieved. Mesoporous silica in diverse shapes and morphologies were achieved by processing the precursor. When the PS tail length was increased, the pore size expanded accordingly. Moreover, such pyrolyzed, ordered mesoporous silica can help to increase both efficiency and stability of nanocatalysts.

Automated summary

Hexagonal mesoporous silica was prepared from single-source giant surfactants constructed using DPOSS and PS, yielding high porosity and a uniform pore size distribution. Varying PS tail lengths can adjust pore size, enhancing both efficiency and stability of nanocatalysts.