4.8 Article

A liquid e-fuel cell operating at 20 °C

Journal

JOURNAL OF POWER SOURCES
Volume 506, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2021.230198

Keywords

E-Fuel; Liquid e-fuel cells; Sub-zero environment; Power density; Energy efficiency; Fuel cell electric vehicles

Funding

  1. Research Grant Council of the Hong Kong Special Administrative Region, China [T23-601/17-R]

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This study introduces a liquid e-fuel cell system based on vanadium ions, which can generate electricity stably at temperatures as low as 20 degrees Celsius, outperforming traditional liquid alcohol fuel cells in sub-zero environments.
An electrically rechargeable liquid fuel (e-fuel) system, which comprises an e-fuel charger and an e-fuel cell, has recently been proposed and proven as an effective approach for storing renewable energy. Potential e-fuels are stated to be obtainable from various electroactive materials including metal ions. In this work, a liquid e-fuel made of vanadium ions for anodic reaction is introduced. Utilizing this e-fuel paired with oxygen at the cathode side, the operation of a liquid e-fuel cell, capable of generating electricity stably at sub-zero cell temperature as low as 20 degrees C, without involving any form of internal or external heating system is demonstrated. At 20. C, this liquid e-fuel cell demonstrates a peak power density of 76.8 mW cm(-2) and an energy efficiency of 25.2% at 30 mA cm(-2), which outperforms all the conventional direct liquid alcohol fuel cells operating under sub-zero environment and even at room temperatures. The successful operation of this e-fuel cell, with its competence and impressive performance at sub-zero temperatures, even at the first time of its demonstration, opens a significant window of opportunity towards the advancement of fuel cell technology, particularly for energizing future fuel cell electric vehicles with an all-climate operation.

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