Facile Fabrication of Highly Stable and Wavelength-Tunable Tin Based Perovskite Materials with Enhanced Quantum Yield via the Cation Transformation Reaction

Metal halide perovskites have attracted great attention for their superior light energy conversion applications. Herein, we demonstrated a facile synthesis of zero-dimensional Sn2+ perovskite Cs4-xMxSnBr6 (M = K+ and Rb+) material through the cation transformation reaction at room temperature. Cs4SnBr6 NCs was mixed with pure metal bromide salts (KBr and RbBr) via the mechanochemical process to successfully synthesize Cs4-xMxSnBr6 perovskite where transformation of Cs to mixed Cs/Rb and mixed Cs/K was achieved. By substituting different cations, the bright fluorescence of the Cs4-xMxSnBr6 was tuned from dim green to greenish-cyan while achieving the photoluminescence (PL) quantum yield of similar to 39%. The crystal structure of Sn based perovskite with the substitution of K+ or Rb+ cations was determined by X-ray diffraction (XRD). Moreover, the Cs4-xMxSnBr6 demonstrated superior air stability and exhibited a better photocatalytic activity for CO2 reduction reaction (CO2RR) with high selectivity of CH4 gas with a higher yield rate compared to the pristine Cs4SnBr6 NCs.

Automated summary

Metal halide perovskites have attracted attention for their light energy conversion applications. A simple synthesis method was used to create zero-dimensional Sn2+ perovskite Cs4-xMxSnBr6 with tunable fluorescence properties and high photoluminescence quantum yield. The Cs4-xMxSnBr6 showed superior air stability and enhanced photocatalytic activity for CO2 reduction, producing high yields of CH4 gas.