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Critical Review on the Physical Properties of Gallium-Based Liquid Metals and Selected Pathways for Their Alteration

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 125, Issue 37, Pages 20113-20142

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.1c05859

Keywords

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Funding

  1. National Natural Science Foundation of China [21922303]
  2. Guangdong Basic and Applied Basic Research Foundation [2020B1515020045]
  3. Shenzhen Municipality Science and Technology Planning Project [SGLH20180622151607182]

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Gallium-based liquid metals have unique properties such as high surface tension, density anomaly, high electrical and thermal conductivity. Despite numerous reports on the physical properties of gallium-based liquid metals, there is significant scatter and inconsistency among the findings. It is necessary to compile literature data, identify general relationships, and address inconsistencies to provide science-based values for researchers.
Gallium-based liquid metals have gained plenty of attention in the scientific community due to their extraordinary properties. The most intriguing properties of liquid metals are high surface tension, density anomaly, high electrical and thermal conductivity, phase transition, and their temperature and low viscosity in combination with their low toxicity. Though there are many reports of the physical properties of gallium-based liquid metals, some of these are highly scattered and inconsistent. Therefore, we compile literature data of these aspects of gallium-based liquid metals, point out general relationships of these physical parameters, and unravel inconsistencies in the literature. Subsequently, we state reasons for the observed scatter and recommend science-based values researchers should employ. Furthermore, we discuss important dependencies between the physical parameters, introduce methods to alter the physical parameters, and introduce selected applications based on changing the physical properties. Finally, we point out open questions concerned with the physical parameters of liquid metals, which should be investigated in the future.

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