4.6 Article

A more flexible salamo-based colorimetric and proportional chemical sensor with fast, highly sensitive and recyclable detection of cyanide and application in test paper

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2021.113271

Keywords

Colorimetric sensor; Fluorescent sensor; Cyanide sensing; Reversibility; Test strip

Funding

  1. National Natural Science Foundation of China [21761018]
  2. Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University [201706]

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A new flexible chemical sensor DNTS has been designed and synthesized, featuring dual modes of colorimetry and luminescence turn on for cyanide detection. The sensor has shown high sensitivity and repeatability through detailed performance and recognition mechanism studies, making it a promising device for cyanide detection based on successful development of test strips.
A more flexible salamo-based chemical sensor DNTS was designed and synthesized, with dual modes of colorimetry and luminescence turn on to sense CN-. The performance of the sensor DNTS has been studied in detail through UV and fluorescence spectroscopy. Meanwhile, the recognition mechanism has been reasonably proved that the interaction between DNTS and CN- leads to the deprotonation of the hydroxyl group, followed by the ?-? stacking process, resulting in luminescence. The sensor DNTS can detect cyanide with high sensitivity through proportional fluorescence (398/468 nm), and its detection limit is about 0.128 ?M. In addition, the successful used of the Cu2+ and CN- coordination mechanism making the sensor repeatable. In short, the sensor DNTS will be a promising device for detecting cyanide based on the successful development of test strips.

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