Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 15, Pages 10166-10176Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00898
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Funding
- National Training Programs of Innovation and Entrepreneurship for Undergraduates [201910055087, 202010055079, 202110055069]
- Chemistry College of Nankai University
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A highly efficient strategy has been developed for the direct thiolation of phenols under transition metal-free and solvent-free conditions. The reactions are operationally simple and employ air as an ideal oxidant, providing mono- and dithiolation products in good to excellent yields under basic conditions. This method tolerates a broad range of aryl thiols and arenes, making it especially applicable for large-scale synthesis.
A highly efficient strategy for the direct thiolation of phenols under transition metal-free and solvent-free conditions has been developed. These reactions are operationally simple with employing air (molecular oxygen) as an ideal oxidant and can selectively provide mono- and dithiolation products in good to excellent yields under basic conditions. The reaction tolerates a broad range of aryl thiols and arenes and is especially applicable for large-scale synthesis.
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