Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 14, Pages 9802-9810Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01193
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Funding
- Japanese Society for the Promotion of Science (JSPS)/the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan [20H02867]
- Sumitomo foundation
- Naito foundation
- Grants-in-Aid for Scientific Research [20H02867] Funding Source: KAKEN
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The core scaffold of paspaline-type indole-terpenes was synthesized using the House-Meinwald rearrangement as a key step, successfully constructing contiguous asymmetric quaternary carbon centers.
The core scaffold of paspaline-type indole-terpenes was synthesized by using the House-Meinwald rearrangement as a key step. Rearrangement of the epoxide methyl group in the precursor with methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) as a Lewis acid proceeded smoothly to construct contiguous asymmetric quaternary carbon centers by a 1,2-chirality transfer.
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