Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 13, Pages 9067-9075Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01031
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Funding
- National Natural Science Foundation of China [21472133]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Key Laboratory of Organic Synthesis of Jiangsu Province [KJS1749]
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A new method for the preparation of carbamates using copper-catalyzed cross-coupling reaction is described, which is environmentally friendly and compatible with a wide range of amines.
A new approach for the preparation of carbamates via the copper-catalyzed cross-coupling reaction of amines with alkoxycarbonyl radicals generated from carbazates is described. This environmentally friendly protocol takes place under mild conditions and is compatible with a wide range of amines, including aromatic/aliphatic and primary/secondary substrates.
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