Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 13, Pages 9055-9066Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01022
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Funding
- National Natural Science Foundation of China [21971224, 22071222]
- 111 Project [D20003]
- Key Research Projects of Universities in Henan Province [20A150006, 21A150053]
- Natural Science Foundation of Henan Province [202300410375]
- Henan Postdoctoral Foundation
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A visible-light-induced decarboxylation reaction was developed for the synthesis of alkylated benzimidazo[2,1-a]isoquinoline-6(5H)-ones and indolo[2,1-a]isoquinolin-6(5H)-ones under metal-free conditions, effectively avoiding the use of metal catalysts and traditionally volatile organic solvents.
A visible-light-induced decarboxylation reaction was developed for the synthesis of alkylated benzimidazo[2,1-a]isoquinoline-6(5H)-ones and indolo[2,1-a]isoquinolin-6(5H)-ones under metal-free conditions. Impressively, metal catalysts and traditionally volatile organic solvents could be effectively avoided.
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