Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 14, Pages 9384-9395Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00617
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Funding
- National Natural Science Foundation of China [22061031]
- Natural Science Foundation of Inner Mongolia of China [2020MS02013]
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This novel palladium-catalyzed aryl-furanylation of alkenes provides a straightforward route to various benzofuran-containing 3,3-disubstituted oxindole derivatives bearing a quarternary carbon center. In a single chemical operation, one C(sp(2))-O bond, two C(sp(2))C(sp(3)) bonds, an oxindole, and a furan ring are formed in the cascade process.
A novel palladium-catalyzed aryl-furanylation of alkenes is described. This protocol provided a straightforward route to the synthesis of various benzofuran-containing 3,3-disubstitutedoxindole derivatives bearing a quarternary carbon center. In the cascade process, one C(sp(2))-O bond, two C(sp(2))C(sp(3)) bonds, an oxindole, and a furan ring are formed in a single chemical operation.
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