Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 86, Issue 14, Pages 9914-9923Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01100
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Funding
- National Key Research and Development Plan [2017YFD0200504]
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A novel three-component reaction catalyzed by CuO in water has been developed, allowing the synthesis of a wide range of products containing 1,3/1,4-diketones. This method offers advantages such as the use of readily available starting materials, wide substrate scopes, excellent yields, gram-scale synthesis, and mild reaction conditions.
A novel three-component reaction of alpha-ketoaldehydes, 1,3-dicarbonyl compounds, and organic boronic acids catalyzed by CuO in water has been developed to give a wide range of products containing 1,3/1,4-diketones. The method has some advantages such as the use of readily available starting materials, wide substrate scopes, excellent yields, gram-scale synthesis, and mild reaction conditions.
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