4.1 Article

Effect of external electric field on the formation of colloidal Ag-Au alloy nanoparticles through laser post-irradiation

Journal

JOURNAL OF NANOPHOTONICS
Volume 15, Issue 2, Pages -

Publisher

SPIE-SOC PHOTO-OPTICAL INSTRUMENTATION ENGINEERS
DOI: 10.1117/1.JNP.15.026009

Keywords

laser ablation; Ag-Au alloy nanoparticles; laser-induced synthesis; surface plasmon resonance; electric field

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In this study, Ag-Au alloy nanoparticles were successfully synthesized by post-irradiation with nanosecond pulse laser in the presence of an external electric field. The results showed that the electric field significantly reduced the formation time of Ag-Au alloy and decreased the localized surface plasmon resonance wavelength of the alloy nanoparticles.
We report the synthesis of Ag-Au alloy nanoparticles (NPs) by post-irradiation of mixed colloidal Ag and Au NPs by a nanosecond pulse laser in the presence of an external electric field (EEF). In our study, size, optical, and plasmonic properties of colloidal Ag-Au alloy NPs were investigated. A colloid of individual Ag and Au NPs were separately prepared by nanosecond pulsed laser ablation in distilled water. An appropriate volume of these colloidal NPs samples was mixed and post-irradiated with the same pulsed laser beam in the presence of a uniform electric field, resulting in the formation of Ag-Au alloy NPs. The synthesized colloidal alloy NPs were characterized using scanning electron microscopy and UV-vis absorption spectroscopy. The results indicate that the EEF can reduce significantly the Ag-Au alloy formation time. The results also show that the wavelength of the localized surface plasmon resonance of alloy NPs decreased by the applied electric field. (C) 2021 Society of Photo-Optical Instrumentation Engineers (SPIE)

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