Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1248, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2021.131510
Keywords
Dyes; Photocatalysis; Structure; Density of states
Categories
Funding
- King Saud University, Riyadh, Saudi Arabia [RSP-2021/141]
- Shenzhen Peacock Plan (Research and Development and Industrialization of in vitro Diagnostic Nanomaterials for Tumors) [KQTD2016022920325195]
Ask authors/readers for more resources
A new Ag(I)-based coordination polymer was synthesized and demonstrated to exhibit efficient photocatalytic performance in degrading dyes under UV light. The photodegradation mechanisms were proposed using LC-MS and theoretical analyses.
A new Ag(I)-based coordination polymer (CP) with formula [Ag(H3L)(2)(tib)] (1) (H-4 L = 1,3-bis(3,5-dicarboxylphenoxy)benzoic acid and tib=1,3,5-tris(1-imidazolyl) benzene) was prepared under hydrothermal condition and full characterized. 1 shows a 3D 2-fold interpenetrated network built by supramolecular interactions. It exhibits efficient photocatalytic performance to photodegrade methylene blue (MB), methyl violet (MV), Rhodamine B (Rh B) under UV light. In presence of 1, about 70.27%, 71.24% and 61.14% degradation of MB, MV and Rh B have been found after 100 min, respectively. The plausible photodegradation pathways for MB dye has been proposed using LC-MS and photocatalytic mechanism explained theoretically using band calculations and Hirshfeld surface analyses. (C) 2021 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available