4.7 Article

Effect of organic solvents on the conductivity of polyethylene glycol-based deep eutectic solvents

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 346, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2021.117038

Keywords

Deep eutectic solvents; Electrical conductivity; Molar conductivity; Thermodynamics; Polyethylene glycol

Funding

  1. Natural Science Foundation of Hebei Province [B2019408018]
  2. Fundamental Research Funds for the Universities in Hebei Province [JYQ201902]
  3. Program for the Top Young Talents of Higher Learning Institutions of Hebei Province [BJ2020047]
  4. College Students' Innovation and Entrepreneurship Training Program Project Fund of Langfang Normal University [S202110100001, Y202110100004]

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The effect of organic solvents on the conductivity of PEG-based DESs is investigated, and it is found that the presence of organic solvents can change the conductivity of PEG-based DESs depending on the concentration. The effect on the molar conductivity is different from the conclusion of conductivity.
Conductivity of biocompatible polyethylene glycol (PEG)-based deep eutectic solvents (DESs) is one of the key physical properties for the application of DESs. However, the effect of organic solvents on the conductivity of PEG-based DESs is not investigated to the best of our knowledge. Here, several common organic solvents are selected as the representative solvents. The presence of organic solvents in PEG-based DESs could change the conductivity depending on the concentration. Too low and too high concentration would lead to a low conductivity, while the moderate concentration would lead to a maximal concentration in the whole concentration range. Furthermore, the effect of solvents on the molar conductivity is also derived, which is different from the conclusion of conductivity. This work would provide novel methods for tuning the conductivity of PEG-based DESs for more widespread industrial application. (C) 2021 Elsevier B.V. All rights reserved.

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