4.7 Article

Stability influence factors and mechanism of produced emulsion from CO2 flooding

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 333, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2021.115974

Keywords

CO2 flooding; Produced fluids; W/O emulsions; Stability; Influence factors; Particle

Funding

  1. National Natural Science Foundation of China [51774309]
  2. China National Postdoctoral Program for Innovative Talents [BX20200386]
  3. Key Research and Development Plan of Shandong Province [2019GGX102074]
  4. Fundamental Research Funds for the Central Universities [18CX02166A, 20CX06093A]
  5. Graduate School Innovation program of China University of Petroleum [YCX2019018]

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The study investigated the stability of simulated emulsions from CO2 flooding, showing that stability increased with CO2 pressure but decreased with temperature, while NaCl concentration and pH had little effect. Solid particles had a significant impact on emulsion stability, with those dispersed in the oil phase leading to greater stability.
CO2 flooding has been widely applied for enhanced oil recovery (EOR) in recent years, while the difficulty in demulsification of the produced fluid has become an urgent problem due to the specific physical and chemical properties of CO2 flooding process. In this study, the crude oil from Block Hei-59 by CO2 flooding was used to prepare simulated produced emulsions and the influence of CO2 pressure, temperature, salinity, pH and solid particles on the stability of emulsions are investigated. The results indicated that the stability of simulated emulsions gradually increased with CO2 pressure but decreased with the increase of temperature, while the change of NaCl concentration and pH had little effects on the stability of emulsions. Moreover, the solid particles had great influences on the stability of the emulsion, and the emulsion prepared by the particles initially dispersed in the oil phase was more stable than in water. This study can provide a theoretical basis for the future dehydration and demulsification treatment of produced fluids from the formation developed by CO2 flooding. (C) 2021 Elsevier B.V. All rights reserved.

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