Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 343, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molliq.2021.117644
Keywords
Binary mixtures; Ionic liquids; Preferential solvation; Preferential-solvation index; Solvent-exchange model
Funding
- Fondecyt [1190045]
- Brazilian Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)
- Brazilian Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) [001]
- Brazilian Fundacao de Amparo a Pesquisa e Inovacao do Estado de Santa Catarina (FAPESC)
- Brazilian UFSC
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The study discusses the applications of a preferential-solvation index in comparing analogous binary mixtures with ILs, analyzing over sixty examples from the literature. Interesting trends and patterns are revealed, questioning the meaning of fitting parameters from classic models and the existence of postulated entities in binary mixtures of ILs.
Applications of a preferential-solvation index (PSI) for comparing analogous binary mixtures with ionic liquids (ILs) are described with the analysis of more than sixty examples from the literature. Interesting trends and patterns are revealed, confirming conclusions based on more elaborate treatments, or disclosing puzzling discontinuities by comparison of analogous mixtures. The obtained trends also question the meaning of fitting parameters from classic models of preferential solvation and the existence of postulated entities that are hard to be conceived in binary mixtures of ILs. (C) 2021 Elsevier B.V. All rights reserved.
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