4.6 Article

Pressure-tunable thermal conductivity observed for bisamide functionalized diacetylene crystals

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A Series of Bisamide-Substituted Diacetylenes Exhibiting a Terminal Alkyl Odd/Even Parity Effect on Mechanoactivated Photopolymerization

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Summary: The study showed that mechanoresponsive bisamide substituted diacetylenes can switch between light-inert and light-reactive states under certain pressure, related to pressure-induced crystalline phase transition. The research found that the odd/even parity of terminal alkyl spacer length plays a key role in determining the intrinsic intermolecular hydrogen-bonding nature of DA crystals and the resultant molecular packing.

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