Journal
JOURNAL OF INTELLIGENT MATERIAL SYSTEMS AND STRUCTURES
Volume 33, Issue 4, Pages 547-557Publisher
SAGE PUBLICATIONS LTD
DOI: 10.1177/1045389X211023587
Keywords
Shape memory polymer; grapheme; near-infrared light; photothermal filler
Categories
Funding
- TSRI Fund [CU FRB640001 01 21 1]
- Basic Research Fund (Blue Sky) of the National Research Council of Thailand
- 90th Anniversary of Chulalongkorn University Scholarship
- Ratchadaphiseksomphot Endowment Fund of Chulalongkorn University
- National Nanotechnology Center (NANOTEC), NSTDA, Ministry of Science and Technology, Thailand, through its Research Network NANOTEC (RNN) program
- Aditya Birla Chemicals (Bangkok, Thailand)
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Incorporation of graphene nanoplatelets as photothermal fillers significantly improved the photothermal, thermal, and dynamic mechanical properties of the bio-based benzoxazine/epoxy copolymers. The addition of 3 wt% GNPs resulted in the highest shape memory performance with shape fixity of 92% and shape recovery of 99%, demonstrating excellent shape memory properties. Additionally, the V-fa/ECO copolymers filled with GNPs showed good execution in repeated fold-deploy tests, with shape fixity and shape recovery values close to the original specimen.
Novel near-infrared (NIR) light-induced bio-based shape memory polymers (SMPs) were prepared from copolymers of vanillin/furfurylamine-based benzoxazine monomer (V-fa monomer) and epoxidized castor oil (ECO). Incorporation of graphene nanoplatelets (GNPs) as photothermal fillers into the copolymers provided shape memory properties under near-infrared (NIR) light actuation. The effects of GNP content on photothermal, thermal, dynamic mechanical, morphology, and shape memory properties of the bio-based benzoxazine/epoxy copolymers (V-fa/ECO copolymers) were investigated. The results showed that the addition of GNPs significantly improved the photothermal, thermal, and dynamic mechanical properties of the copolymers. The uniform dispersion of 3 wt% GNPs in the V-fa/ECO copolymers resulted in the highest shape memory performance with shape fixity of 92% and shape recovery of 99% upon NIR light actuation. The recovery time decreased with the increment of GNP content, and the V-fa/ECO copolymers filled with GNPs displayed good execution in the repeated fold-deploy, in which the shape fixity and shape recovery values were close to the original specimen. Therefore, the outstanding properties of V-fa/ECO copolymers filled with GNPs had a potential to be excellent SMPs under NIR actuation.
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