Journal
JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 290, Issue -, Pages -Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2021.112593
Keywords
Nutrient recovery; Magnesium chloride; Zeolite; Digestate; Sewage sludge; Cattail
Categories
Funding
- Slovenian Ministry of Education, Science and Sport [C333019952041, OP20.04349]
- Slovenian Research Agency [P2-0412, P2-0032]
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The study found that co-digestion of sewage sludge and cattail enhanced biogas production, with different methods showing variations in phosphorus and nitrogen recovery efficiency, and the two-step recovery method using granulated zeolite was the most effective.
The aim of this study was to recover nutrients (NPK and other) from the liquid fraction of digestate obtained by rumen fluid enhanced anaerobic co-digestion of sewage sludge and cattail (Typha latifolia grass). Firstly, anaerobic digestion (AD) studies were performed to examine the biogas potential of selected substrates. The liquid fraction of digestate was then used in nutrient recovery experiments. Four methods were applied to recover nutrients: i) conventional struvite precipitation by MgCl2, ii) simultaneous precipitation and ion exchange by Na-zeolite, and iii) two-step recovery using precipitation, followed by ion exchange with powdered or iv) granulated Na-zeolite. The products of nutrient recovery were characterised using different chemical methods and the cress seed germination test was performed to evaluate their fertility potential. The results show that co-digestion of sewage sludge with cattail enhanced biogas production by almost 50 vol %. The addition of rumen fluid positively contributed to the degradation of lignocellulosic materials and to biogas production. In all of the recovery methods tested, phosphorus was successfully recovered with efficiency of more than 99 wt%. Nitrogen recovery was less efficient than phosphorus recovery, 85-92 wt%. Simultaneous precipitation and ion exchange lowered nitrogen recovery efficiency compared to classical struvite precipitation, while sequential precipitation and ion exchange resulted in improvement. The most efficient method was twostep recovery using granulated zeolite. The precipitates consisted of different Mg and K-phosphates in quite irregular shapes. The struvite and K-struvite were detected in low quantities. The precipitates contained more than 25 wt% of macronutrients (NPK), exhibited effective utilization of nutrients by plants, and showed good fertility potential. Precipitate mixed with powdered Na-zeolite promises to be interesting for further agricultural use, as zeolite offers several potential improvements for soil. Both zeolites exhibited good performance in the recovery of K+ ions.
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