4.7 Article

Micro-bubbles enhanced removal of diesel oil from the contaminated soil in washing/flushing with surfactant and additives

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 290, Issue -, Pages -

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2021.112570

Keywords

Diesel contaminated soil; Soil washing; flushing; Remediation enhancement; Bio-surfactant; Microbubbles

Funding

  1. National Key R&D Program of China [YFC0408503]
  2. National Key Research and Development Program of China [2016YFC0400501, 2016YFC0400502]
  3. Fundamental Research Funds for Central Universities [2232018D343, CUSFDHD2017096]
  4. National Natural Science Foundation of China [21277023]
  5. China Scholarship Council

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Enhanced diesel removal from contaminated soil was achieved by using micro-bubbles and selected surfactants based on their solubilization properties and decontamination capacities. The use of a mixture solution of saponin and cyclodextrin, as well as micro-bubble enhancement, significantly increased diesel removal efficiency. Moreover, a 90-minute flushing time with circulation of flushing solution effectively ensured the cleaning goal while retaining soil solute for residual diesel biodegradation.
Diesel removal of contaminated soil by washing/flushing was enhanced with micro-bubbles and selected surfactants based on their solubilization properties and decontamination capacities. The influencing factors were studied to aim for increasing washing/flushing efficacy. The mixture solution of saponin and cyclodextrin increased the removal efficiency significantly compared to the single-agent solution flushing with an increasing range of 20%-31%. Meanwhile, micro-bubble enhancement increased over 20% of the diesel removal for the sandy soil flushing. As the flushing process may cause soil eroded, the TDS and soil solute in flushing solution were measured to evaluate the circulation time. The 90 min flushing time ensured the cleaning goal and reserved the soil solute by circulation flushing. The soil solute, especially the electron acceptor (NO3- ) , was remained in the soil, which was highly demanded for residual diesel biodegradation of loam soil. It is concluded that mixed agents, circulation of flushing solution, and micro-bubbles increased the diesel removal, and the circulation flushing could be very promising in practical applications.

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