4.7 Article

New insights into the phenacyl bromide electroreduction: Unambiguously characterized 5,5′-bis(3,5-diaryl-2(5H)-furanone). Anodic oxidation of 2,4-diphenylfuran ☆

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 892, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2021.115265

Keywords

2; 4-Diarylfurans; Electrochemical reduction; Butenolides; Anodic oxidation; Radical homocoupling; Endoperoxide intermediate; Autooxidation reaction; Furan-based oligomers

Funding

  1. University of Alcala [CCG2019/CC-033, CCG2018/EXP-030]
  2. Spanish Ministry of Science, Innovation and Universities [PEJ2018-002710-A]

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New attempts and insights have been made in the electrochemical potentiostatic reduction of phenacyl bromides in DMF. This study presents evidence on the original mechanism proposal, definitive characterization of the obtained products, and additional results of complementary electrochemical anodic reactions.
New attempts and insights are reported on the electrochemical potentiostatic reduction of phenacyl bromides in DMF. Now we present the evidences on the original mechanism proposal, the definitive characterization of the obtained products and additional results of complementary electrochemical anodic reactions.

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