A surface charge governed nanofluidic diode based on a single polydimethylsiloxane (PDMS) nanochannel

Hypothesis: Nanofluidic diodes have attracted intense attention recently. Commonly used materials to design these devices are membrane-based short nanopores and aligned Carbon nanotube bundles. It is highly desirable and very challenging to develop a nanofluidic diode based on a single PDMS nanochannel which is easier to be introduced into an integrated electronic system on a chip. Layer-by-layer (LBL) deposition of charged polyelectrolytes can change the size and surface properties of PDMS nanochannels that provides new possibilities to develop high-performance nanofluidic based on PDMS nanochannels. Experiments: A novel design of nanofluidic diode is presented by controlling the surface charges and sizes of single PDMS nanochannels by surface modification using polyelectrolytes. Polybrene (PB) and Dextran sulfate (DS) are used to reduce the PDMS nanochannel size to meet the requirement of ion gating by LBL method and generate opposite surface charges at the ends of nanochannels. The parameters of such a nanofluidic diode are investigated systematically. Findings: This nanofluidic diode developed in this work has high effective current rectification performance. The rectification ratio can be as high as 218 which is the best ever reported in PB/DS modified nanochannels. This rectification ratio reduces with high voltage frequency and ionic concentration whereas increases in shorter nanochannels. (c) 2021 Elsevier Inc. All rights reserved.

Automated summary

In this study, a novel nanofluidic diode design was presented by controlling the surface charges and sizes of single PDMS nanochannels through surface modification using polyelectrolytes. The developed nanofluidic diode showed high effective current rectification performance, achieving a rectification ratio as high as 218. The rectification ratio decreases with high voltage frequency and ionic concentration, while it increases in shorter nanochannels.