Surface engineering induced superstructure Ta2O5-x mesocrystals for enhanced visible light photocatalytic antibiotic degradation

Mesocrystals are types of fascinating multifunctional materials in fabricating rapid charge transport pathways, and surface engineering could be considered as a significant influencing factor in boosting charge separation for efficient photocatalytic application. In this work, surface engineered Ta2O5-x mesocrystals were synthesized by facile alkali treatment strategy for enhanced visible light photocatalytic tetracycline degradation. The highly enhanced photocatalytic activity could be attributed to the highly increased surface areas and surface hydroxyl groups to compare with those of commercial Ta2O5 and pristine Ta2O5-x mesocrystals, which could provide more surface reactive sites and high electron density center for trapping photo-generated holes. Besides, possible tetracycline transformation pathways over surface engineered Ta2O5-x mesocrystals and visible light photocatalytic mechanism were also proposed in this work. Current work also provides a facile strategy for regulating surface property of ultrawide bandgaps semiconductors for enhanced visible light photocatalytic performance. (C) 2021 Elsevier Inc. All rights reserved.

Automated summary

Mesocrystals are fascinating multifunctional materials that can create rapid charge transport pathways, and surface engineering plays a significant role in boosting charge separation for efficient photocatalytic application. In this study, surface-engineered Ta2O5-x mesocrystals were synthesized, leading to enhanced visible light photocatalytic activity. The increased surface areas and surface hydroxyl groups compared to commercial Ta2O5 and pristine Ta2O5-x mesocrystals provide more surface reactive sites and high electron density centers for trapping photo-generated holes.