4.7 Article

Comb-like structural modification stabilizes polyvinylidene fluoride membranes to realize thermal-regulated sustainable transportation efficiency

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 591, Issue -, Pages 173-183

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.01.091

Keywords

Comb-like copolymer; Antifouling; Fluid transportation; Separation membrane; Antibacterial surface

Funding

  1. Natural Science Foundation of China [51673175]
  2. Natural Science Foundation of Zhejiang Province [LZ20E030004, LY16E030012]

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The study demonstrates that the unique structural design of grafted copolymers effectively prevents bacteria adhesion and provides reversible surface wettability. This design not only improves the fouling resistance of the membrane, but also enhances the variable water fluid transport efficiency.
copolymers to the membrane. Such unique structural design of grafted copolymer, containing hydrophilic side chain and temperature-responsive chain backbone, stably prevents bacteria adhesion and provides reversible surface wettability. Therefore, the resultant membranes were evaluated to prevent bacterial adhesion, high touch-killing efficiency and temperature-controlled contaminants release (-99% of protein and -75% of bacteria). Moreover, with the collapse and stretch of grafted copolymer chain backbone, the synthetic membrane further reversibly adjusted inner micro-porous structure and surface wettability, which eventually helped to achieve variable water fluid transport efficiency. This study not only provides a feasible structural design for stably coping with the challenging of antifouling and subsequent contamination adhesion of PVDF membrane, but also potentially answers the significant gap between lab research advances and practical application, particularly in the industrial membrane field.

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