4.7 Article

Ex-ante LCA of emerging carbon steel slag treatment technologies: Fast forwarding lab observations to industrial-scale production

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 313, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.127921

Keywords

Carbon steel slag; Ex-ante LCA; Upscaling; Chromium recovery; By-product valorisation

Funding

  1. Research Foundation Flanders (FWO-Vlaanderen) [1207520N]
  2. European Union's Horizon 2020 Research and Innovation program [730471]
  3. H2020 Societal Challenges Programme [730471] Funding Source: H2020 Societal Challenges Programme

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In this study, a ex-ante life cycle assessment was used to evaluate a novel technological pathway for extracting chromium from carbon steel slag and valorizing the residual matrix material. The research showed that using simple calculation rules in combination with basic design principles for processes at an industrial scale is more efficient than a fully-fledged process design from the start.
The valuable properties of carbon steel slag are currently underexploited. To date, research mainly focusses on valorising a single property of the slag. In this study an ex-ante life cycle assessment (LCA) was applied to evaluate the environmental profile of a novel technological pathway aimed at the extraction of chromium from carbon steel slag in combination with high quality valorisation of the residual matrix material. A comparison with current practice was made, not only by calculating the environmental impact of the lab scale observations, but more importantly by estimating the impact on an industrial scale. Practical guidance on ex-ante LCA is limited, so this study contributes by incorporating simulations on thermodynamic behaviour, complemented with empirical calculation rules and including information derived from similar technologies to perform the upscaling. These principles of ex-ante LCA were applied to the lab results of two consecutive research iterations. Substantial improvements of the environmental profile were observed: ex-ante results turned out to be a factor 20 lower compared to the results from the lab observations after the first iteration and had decreased by a factor 2 compared to the small pilot scale of the second iteration. All upscaled results are better than those from the worst case reference scenario (landfill). Based on the experience gained after this iterative research cycle, a practical recommendation is that at a low technology readiness level using more simple calculation rules in combination with a flowsheet based on elementary design principles for processes at an industrial scale is a more efficient way of modelling compared to a fully-fledged process design from the start.

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