Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 160, Issue -, Pages -Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2021.106509
Keywords
Liquid-liquid equilibria; Mesityl oxide; Cyclohexanone; NRTL; UNIQUAC
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The liquid-liquid equilibrium data of the ternary mixture of water, cyclohexanone, and mesityl oxide at different temperatures and pressures were presented. The distribution coefficient and separation factor were used to assess the efficiency of extracting cyclohexanone from water. The NRTL and UNIQUAC models successfully correlated the experimental data with good reliability.
To separate and purify cyclohexanone from water, in 101.3 kPa, 298.2, 303.2 and 313.2 K, the liquid-liquid equilibrium (LLE) data of the ternary mixture of water + cyclohexanone (CYC) + mesityl oxide were presented. The distribution coefficient (D) and separation factor (S) appraised the utility of extracting cyclohexanone from water. The NRTL and UNIQUAC models successfully correlated the experimental data with RMSD less than 0.29%. The GUI-MATLAB tool was used to verify the good reliability of the regression parameters. (c) 2021 Elsevier Ltd.
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