4.7 Article

Novel Insights into Inkjet Printed Silver Nanowires Flexible Transparent Conductive Films

Journal

Publisher

MDPI
DOI: 10.3390/ijms22147719

Keywords

silver nanowires ink; flexible transparent conductive films; inkjet printing; well-defined pattern

Funding

  1. Grant for National Natural Science Foundation of China [61671140]
  2. Zhongshan Science and Technology Projects [2019B2016]
  3. Youth Innovation Talent Project
  4. Special Projects in Key Areas for the Universities of Guangdong Province [2019KQNCX190, 2020ZDZX2027]
  5. Characteristic Innovation Project for the Universities of Guangdong Province [2019KTSCX210]
  6. Science and Technology Foundation of Guangdong Province [2021A0101180005]

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By investigating the factors influencing silver nanowire inkjet printing and fabricating flexible transparent conductive films on PET substrates, it was demonstrated that well-defined patterns with good photoelectric properties can be obtained.
Silver nanowire (AgNWs) inks for inkjet printing were prepared and the effects of the solvent system, wetting agent, AgNWs suspension on the viscosity, surface tension, contact angle between ink droplet and poly(ethylene) terephthalate (PET) surface, and pH value of AgNWs ink were discussed. Further, AgNWs flexible transparent conductive films were fabricated by using inkjet printing process on the PET substrate, and the effects of the number printing layer, heat treatment temperature, drop frequency, and number of nozzle on the microstructures and photoelectric properties of AgNWs films were investigated in detail. The experimental results demonstrated that the 14-layer AgNWs printed film heated at 60 degrees C and 70 degrees C had an average sheet resistance of 13 omega center dot sq(-1) and 23 omega center dot sq(-1) and average transparency of 81.9% and 83.1%, respectively, and displayed good photoelectric performance when the inkjet printing parameters were set to the voltage of 20 V, number of nozzles of 16, drop frequency of 7000 Hz, droplet spacing of 15 mu m, PET substrate temperatures of 40 degrees C and nozzles of 35 degrees C during printing, and heat treatment at 60 degrees C for 20 min. The accumulation and overflow of AgNWs at the edges of the linear pattern were observed, which resulted in a decrease in printing accuracy. We successfully printed the heart-shaped pattern and then demonstrated that it could work well. This showed that the well-defined pattern with good photoelectric properties can be obtained by using an inkjet printing process with silver nanowires ink as inkjet material.

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