4.7 Article

Revealing the structural heterogeneity of metallic glass: Mechanical and nanoindentation

Journal

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijmecsci.2021.106469

Keywords

Metallic glass; Microstructural heterogeneity; Shear transformation zones; Mechanical spectroscopy; Nanoindentation

Funding

  1. NSFC [51971178, 51871132]
  2. Natural Science Foundation of Shaanxi Province [2021JC12]
  3. Research Grants Council (RGC) through General Research Fund (GRF) [CityU 11200719, CityU11213118, CityU 11209317]

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Microstructural heterogeneity in metallic glasses plays a crucial role in influencing their mechanical and physical properties. Researchers have found that severe plastic deformation can enhance the spatial structural heterogeneity and reduce the energy barrier for shear transformation zones (STZs) activation. The study suggests that decreasing barriers and increasing nucleation sites of STZs during physical aging to rejuvenation may improve the plasticity in metallic glasses.
Microstructural heterogeneity is an important issue in understanding the mechanical and physical properties of metallic glasses (MGs). Theoretically, physical aging below the glass transition temperature relax the MGs systems to a lower potential energy state on the potential landscape (PEL) while the cold rolling rejuvenates MGs to a higher potential energy state. In the current work, we systemically turned the structural heterogeneity through dynamic mechanical relaxation and rejuvenation. Correlations among the structural heterogeneity, internal friction, and shear transformation zones (STZs) of the model alloy was connected. Based on the cooperative shear model and statistical analysis, the scale variation of the STZs was revealed. This study demonstrated that the spatial structural heterogeneity can be enhanced by severe plastic deformation which can reduce the energy barrier for STZs activation. And we proposed the barriers decrease and more nucleation sites of STZs from physical aging to rejuvenation, which may be potential mechanism for improving the plasticity in MGs.

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