Low carbon ultrasonic production of alternate fuel: Operational and mechanistic concerns of the sonochemical process of hydrogen generation under various scenarios

Sonochemistry is considered as one of the cleaner pathways for hydrogen production. The present paper investigates the potential of this technique based upon mass, mass to energy and energy conversion metrics, using modelling and experimental approaches. Four scenarios are examined assuming four saturating gases, namely O-2, air, N-2 and Ar, four acoustic frequencies, i.e., 20, 210, 326 and 488 kHz, and considering common acoustic intensities then common net electric power. The study revealed that Ar is the best fitting saturating gas for the sonochemical production of hydrogen. With a common acoustic intensity of 0.48 W/cm(2), an optimum ratio of H-2 molar yield to acoustic energy intensity is retrieved at 210 kHz, while with a common net electric power of 87 W, the highest ratio of hydrogen yield to electric energy was observed at 20 kHz. Results were interpreted based upon emitter surface, energy conversion and distinction of calorimetric and cavitational energies. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

This study investigates the potential of sonochemistry for hydrogen production, finding that argon is the most suitable saturating gas. Optimal H-2 molar yield ratio occurs at 210 kHz under a specific acoustic intensity, while the highest hydrogen yield ratio is observed at 20 kHz under a specific net electric power.